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Migratory aptitude is the relative ability of a migrating group to migrate in a rearrangement reaction. This can be affected by the leaving group (whichever gives a more stable carbocation)depends upon the electron density of the migrating group i.e. Hydride > Phenyl = Tert-Alkyl > Sec-Alkyl > Primary Alkyl > Methyl The migratory groups follow the order of increasing stability of carbocation instead of carbanion. 〔http://classes.yale.edu/02-03/chem125a/125webSpring/BaeyerVilliger/migratoryaptitude.htm〕 == References == 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「migratory aptitude」の詳細全文を読む スポンサード リンク
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